Biomimetic Nitration of Phenols Using Metalloporphyrins/H2O2/NO2 −
نویسندگان
چکیده
منابع مشابه
A Reinvestigation of Nitration of Phenols with Metal Nitrates under Non-Aqueous and Aprotic Conditions
Nitration of phenol and various 4-substituted phenols with Cu(NO3)2.3H2O, Cu(NO3)2.3H2O/SiO2, 9H2O and Cr(NO3)2. 9H2O in different anhydrous organic solvents are investigated. High selectivity ratio of para vs ortho isomers has been observed. Mono- and dinitro compounds f...
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INTRODUCTION A synthetic water-soluble meso-tetra(2,6-dichloro-3-sulfonatophenyl)porphyrinate of iron(III) chloride, Fe-(TDCPPS)Cl, was employed to catalyze the oxidative co-polymerization of penta-halogenated phenols in two humic materials of different origin. MATERIALS AND METHODS Co-polymerization of pentachlorophenol (PCP) was followed by high-performance size-exclusion chromatography (HP...
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nitration of phenol and various 4-substituted phenols with cu(no3)2.3h2o, cu(no3)2.3h2o/sio2, 9h2o and cr(no3)2. 9h2o in different anhydrous organic solvents are investigated. high selectivity ratio of para vs ortho isomers has been observed. mono- and dinitro compounds from phenol and 4-substituted phenols by choosing the proper solvents and reaction conditions, are also obtained with high sel...
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ژورنال
عنوان ژورنال: Catalysis Letters
سال: 2015
ISSN: 1011-372X,1572-879X
DOI: 10.1007/s10562-015-1610-8